Drifting exposure system for sampling stormwater discharge plumes

ABSTRACT

A drifting buoy sampler system for a stormwater discharge plume formed from stormwater discharged into coastal waters. The system compresan electronics sampling pod for collecting integrated water samples within the stormwater plume as the buoy system drifts with the stormwater plume near the water surface as the plume travels out to sea. The pod includes a watertight section including a GPS/radio module for providing GPS (geo-position) location information and a processor for monitoring and controlling the sampling rate, a pump module and a battery module; a passive sampler bag for collecting the integrated water samples; a free flooding section including a composite sample bag module such that the pump module pumps collected samples from the passive sampler bag to the composite sample bag module at a predetermined sampling rate and a ballast module for providing ballast to the system when drifting within the plume.

FEDERALLY-SPONSORED RESEARCH AND DEVELOPMENT

This invention (Navy Case No. NC 103,249) is assigned to the United States Government and is available for licensing for commercial purposes. Licensing and technical inquiries may be directed to the Office of Research and Technical Applications, Space and Naval Warfare Systems Center, Pacific, Code 72120, San Diego, Calif., 92152; voice (619) 553-2778; email T2@spawar.navy.mil.

BACKGROUND

After rain events, the water discharged into coastal waters is known as stormwater. Stormwater discharges (an example is shown in FIG. 1), can carry with them a host of pollutants in the form of contaminated sediment. These events span coastal sites, including nearly every DoD coastal site, and are linked to all aspects of regulatory compliance including pollution discharge permitting, source control strategies, and environmental restoration programs which cost the Navy hundreds of millions of dollars annually.

The fact that these events do not occur as point sources make them extremely difficult to characterize and control. Sediment transport models often do not have enough resolution to resolve stormwater discharges and current field-based sampling strategies such as sampling near the outfalls only provides indirect evidence as to the transport, impact, and the ultimate fate of the contaminated sediment in the coastal waters.

SUMMARY

A drifting buoy sampler system for a stormwater discharge plume formed from stormwater discharged into coastal waters. The system compresan electronics sampling pod for collecting integrated water samples within the stormwater plume as the buoy system drifts with the stormwater plume near the water surface as the plume travels out to sea. The pod includes a watertight section including a GPS/radio module for providing GPS (geo-position) location information and a processor for monitoring and controlling the sampling rate, a pump module and a battery module; a passive sampler bag for collecting the integrated water samples; a free flooding section including a composite sample bag module such that the pump module pumps collected samples from the passive sampler bag to the composite sample bag module at a predetermined sampling rate and a ballast module for providing ballast to the system when drifting within the plume.

BRIEF DESCRIPTION OF THE DRAWINGS

Throughout the several views, like elements are referenced using like references, wherein:

FIG. 1 shows storm drain and sheet flow discharges at Naval Base San Diego.

FIG. 2 shows a view of a drifting buoy sampler system.

FIG. 3 is a schematic diagram showing a module designed for integrated and passive sampling of a stormwater plume.

FIG. 4 is a schematic showing how a drogue chute and winch system mimics the settling trajectory of a particle-of-interest.

FIG. 5 is a CAD drawing showing the winch system which lowers itself and the drogue chute to the bottom of the seafloor.

DETAILED DESCRIPTION OF THE EMBODIMENTS

Referring to FIGS. 2-3, one embodiment provides a capability to do both composite and passive sampling of the stormwater discharge plume as the plume moves from the source and disperses out in the coastal waters.

The buoy system collects integrated water samples within stormwater discharge plumes in coastal waters as the samples travel away from the source. The system provides the capability to pump seawater collected from the stormwater plume through a passive sampler, such as diffusive gradients in thin films or diffusive equilibrium in thin films and/or into a composite sampler for later laboratory measurements related to the identification and concentration of organic and metal contaminants after the buoy is retrieved.

The buoy system can be equipped with GPS so that the geo-position can be correlated with the types of time-weighted concentration of contaminants from specific sources. The buoy system can also equipped with communications to monitor and control the sampling.

The drifting buoy sampler system drifts with the stormwater plume which stays near the surface as it travels out to sea, as shown in FIG. 2.

One embodiment includes a GPS/communications unit, a pump and composite sampling bag, and a battery and microcontroller for setting the sampling rate. The battery and pump are not exposed to the seawater, while the composite sampling bag can be in a free-flooded chamber (see FIG. 3).

FIG. 3 is a schematic diagram showing the key module designed for integrated and passive sampling of the stormwater plume.

During this time, the buoy system collects composite and passive samples of the seawater and its contents. While collecting an integrated sample, the GPS position of the buoy will be recorded. The combined data provides insight into how specific contaminants disperse from the plume as they are dispersed out into the seawater.

Referring again to FIG. 2, the drifting sampler buoy system 10 drifts with a stormwater plume 14. The plume 14 is shown above the sea water 16 and sediment bed 20 in FIG. 2. As shown in FIG. 2, the buoy system 10 stays near the surface as the buoy system 10 travels out to sea, along with the stormwater plume 14.

FIG. 3 shows a schematic diagram of a module 30 designed for integrated and passive sampling of a stormwater plume. The module 30 includes a GPS/radio mast and antenna 32, floats/tethers 34, sails 36, and electronics/sampling pod 40.

The pod 40, shown in more expanded form in the right side of FIG. 3, includes a watertight section 42, including GPS/radio module 44, battery module 46, passive sampler 50, and pump module 52.

The pod 40 also includes a free flooding section 60, which includes composite sample bag module 62 and ballast module 64.

The system collects an integrated sample of seawater content during the entire period the plume travels out to sea, not just at the source of the plume where the contaminants will be strongest. The system comprises integrating a composite and passive sampling mechanism with the buoy. Because the drifter automatically follows the plume, the entire sampling event can be done autonomously with no operator intervention except to deploy and retrieve the system.

The system allows for linking the sampling time to exposure durations for organisms. For example many toxicity tests are associated with 48-96 hour exposure times. Thus a composite sample collected over that time period would provide a realistic estimate of the concentration that an organism (like a planktonic larvae) that was drifting with the plume would be exposed to.

Many samplers can be released in groups or over time to provide more detailed descriptions and statistical information about the dispersion, concentrations and exposure levels in these plumes. An interface of the sampler and sensors to the user via satellite, cell phone, radio, Bluetooth or WiFi will allow for both monitoring of the sampling process and control of the sampler remotely.

Alternatively, one could bring along multiple composite sampling bags and fill the bags at different periods of time as the buoy drifts away from the source, thereby giving an indication of how the concentrations of contaminants change with distance from the source. The sampling could also be linked to the feedback from various sensors. For instance with feedback from the GPS it could be constrained to sampling in certain spatial areas. With feedback from a salinity sensor, it could be constrained to only sampling while it was in the freshwater storm plume. With feedback from a turbidity sensor it could be linked to sampling when the particle concentrations were in a certain range. The composite sampler could also be replaced by a sorption type column sampler filled with reactive material so that it pre-concentrated certain contaminants of interest.

The system could also utilize passive samplers such as Polyethylene Sampling Devices that can simply be attached to the drifter and equilibrate with the water contaminants over time.

Referring now to FIGS. 4-5, one embodiment of a buoy-system can mimic the transport and deposition of specific sizes of contaminated sediment particles as they travel from the source and eventually settle on the seafloor. A controllable-descent rate underwater winch system lowers an instrument package and drogue to the seafloor. In addition, the buoy-system is equipped with communications to monitor and control the descent rate and detect when it reaches the seafloor.

The drifting particle simulator uses GPS which tracks the buoy location at the surface of the water. Underneath the surface float is a drogue chute and winch system/instrument package which can be lowered to the seafloor at a controlled descent rate (e.g., between 0.1-10 mm/s)—a range that covers a wide swath of various size sediment particles.

Lowering the drogue chute ensures that the buoy drifts laterally with the underwater current at the same velocity as the particles of interest (FIG. 4). The speed at which the chute and winch system is lowered can be controlled to mimic the settling rate of the sediment particle of a particular size with use of a pressure sensor. FIG. 4 shows the settling of the buoy 70 from deployment in a settling trajectory to the deposition position, and finally at the retrieval of the buoy 70.

By using bottom-detection sensors, we can pinpoint precisely the GPS location where the controlled-descent winch/instrument package reaches the seafloor. Using this system, we can determine the depositional footprint of contamination on the seafloor to target for future analysis (impact and fate) and potential cleanup.

The system was designed as a motor-controlled winch mounted within the drogue (to minimize drag effects) that releases a slack line (such as a fishing wire) to provide slack to the negatively buoyant drogue chute and winch system. The winch system is mounted on an instrument package that contains a microcontroller, batteries, along with a pressure sensor and bottom detection sensor to carefully control the descent rate and mark the time when the system reaches the seafloor. This time is matched to the GPS-time monitored at the surface buoy and the coordinates are used to mark the location where the contaminated particles have likely deposited. A drawing of the winch system is provided in FIG. 5.

FIG. 5 is a CAD drawing showing the winch system which lowers itself and the drogue chute to the bottom of the seafloor. The winch system in FIG. 5 includes rotary shaft seal 80; end cap closure 82; bearing 84; motor 86; microcontroller 88; rechargeable battery packs 90; dual piston O-rings 92; and bulkhead connectors 94. Depth and bottom detection sensors (not shown) can be attached to the winch system.

This system tracks the three-dimensional trajectories of sediment originating from a stormwater discharge plume to its final depositional location on the seafloor. The winch/instrument package system can be mounted within the drogue. The system can be lowered to the seafloor at a controllable descent rate without operator intervention. The locations where the particles are deposited provide the capability of future sediment-contaminant analyses of these areas which can provide more information about whether a clean-up is necessary. In addition, any potential cleanups might have lower costs associated with a better understanding of the contaminant footprint and more success by cleaning only areas that require it.

Buoyancy engines could be one possible alternative to lowering the drogue and sensor package with the underwater winch system. However, controlling the very slow descent rate could be difficult. In addition, the buoyancy engine would need to resurface to determine its location and the lag-time associated with resurfacing and re-acquiring GPS could negate this systems usefulness.

A composite or passive water sampling system could provide the capability to sample the sediment as it traverses the water column to determine how the contaminant species change with distance and depth from the source. Additional turbidity sensors could be used to measure how particles concentrations change as a function of distance and depth.

From the above description, it is apparent that various techniques may be used for implementing the concepts of the present invention without departing from its scope. The described embodiments are to be considered in all respects as illustrative and not restrictive. It should also be understood that system is not limited to the particular embodiments described herein, but is capable of many embodiments without departing from the scope of the claims. 

What is claimed is:
 1. A drifting buoy sampler system for a stormwater discharge plume formed from stormwater discharged into coastal waters, the system comprising: an electronics sampling pod for collecting integrated water samples within the stormwater plume as the buoy system drifts with the stormwater plume near the water surface as the plume travels out to sea; the pod including; a watertight section including a GPS/radio module for providing GPS (geo-position) location information and a processor for monitoring and controlling the sampling rate, a pump module and a battery module; a passive sampler bag for collecting the integrated water samples; a free flooding section including a composite sample bag module such that the pump module pumps collected samples from the passive sampler bag to the composite sample bag module at a predetermined sampling rate and a ballast module for providing ballast to the system when drifting within the plume.
 2. The buoy system of claim 1 where the buoy system collects integrated samples of composite and passive samples of seawater and contents within the stormwater plume and records the corresponding buoy GPS position over a predetermined time to provide contaminate dispersal information from the plume.
 3. The buoy system of claim 2 further comprising linking the sampling time for predetermined durations to provide estimates of organic concentration within the plume.
 4. The buoy system of claim 3 further comprising releasing multiple groups of buoy samplers to provide more statistical information. 5, The buoy system of claim 4 further comprising releasing multiple groups of buoy samplers over time to provide more statistical information.
 6. The buoy system of claim 5 further comprising multiple composite sampling bags which sample at different times as the buoy system drifts away from shore to provide an indication of how concentration of any contaminants change with distance from shore.
 7. A drifting buoy sampler system for a stormwater discharge plume formed from stormwater discharged into coastal waters, the system comprising: an electronics sampling pod for collecting integrated water samples within the stormwater plumes as the buoy system drifts with the stormwater plume near the surface as the plume travels out to sea; the pod including a GPS/radio module for providing GPS (geo-position) location information and a processor for monitoring and controlling the sampling rate, a pump module and a battery module; a passive sampler bag; a composite sample bag module such that the pump modules pumps collected samples from the passive sampler bag to the composite sample bag module at a predetermined sampling rate.
 8. The buoy system of claim 7 further comprising a ballast module for providing ballast to the system when drifting within the plume.
 9. The buoy system of claim 8 where the buoy system collects integrated samples of composite and passive samples of seawater and contents within the stormwater plume and records the corresponding buoy GPS position over the predetermined time to provide contaminate dispersal information from the plume.
 10. In a drifting buoy sampler system, the method comprising: collecting integrated water samples within a stormwater discharge plume in coastal waters as the plume travels away from the source discharge out to sea; pumping collected samples through a passive sampler into a composite sampler for later measurements related to identification and concentration of organic and metal contaminants after the buoy is retrieved.
 11. The method of claim 10 further comprising collecting integrated samples of composite and passive samples of seawater and contents within the stormwater plume and recording the corresponding buoy GPS position over a predetermined time to provide contaminate dispersal information from the plume.
 12. The method of claim 11 further comprising linking the sampling time for predetermined durations to provide estimates of organic concentration within the plume.
 13. The method of claim 12 further comprising releasing multiple groups of buoy samplers to provide more statistical information.
 14. The method of claim 13 further comprising releasing multiple groups of buoy samplers over time to provide more statistical information.
 15. The method of claim 14 further comprising multiple composite sampling bags which sample at different times as the buoy system drifts away from shore to provide an indication of how concentration of any contaminants change with distance from shore. 